Proxifier can process connections without a proxy server. You can enable this using the option. When this mode is enabled, Proxifier handles the connections that match the Proxification Rules with the Action set to Direct. The connection will be added to the connection list, the traffic will be counted, etc.
This working mode is identical to working through a proxy server except the connection is established directly from the local computer to the remote one. In this mode, Proxifier can be used as a tool for monitoring network connections and traffic, logging network activity, and making and analyzing traffic dumps of network applications.